Micelle swelling agent derived cavities for increasing hydrophobic organic compound removal efficiency by mesoporous micelle@silica hybrid materials

Y.F. Shi, B. Li, P. Wang, R. Dua, D.Y. Zhao
Microporous and Mesoporous Materials, 155, 252257, (2012)

Micelle swelling agent derived cavities for increasing hydrophobic organic compound removal efficiency by mesoporous micelle@silica hybrid materials

Keywords

Mesoporous, Hybrid material, HOCs removal, Water treatment

Abstract

​Mesoporous micelle@silica hybrid materials with 2D hexagonal mesostructures were synthesized as reusable sorbents for hydrophobic organic compounds (HOCs) removal by a facile one-step aqueous solution synthesis using 3-(trimethoxysily)propyl-octadecyldimethyl-ammonium chloride (TPODAC) as a structure directing agent. The mesopores were generated by adding micelle swelling agent, 1,3,5-trimethyl benzene, during the synthesis and removing it afterward, which was demonstrated to greatly increase the HOC removal efficiency. In this material, TPODAC surfactant is directly anchored on the pore surface of mesoporous silica viasingle bondSisingle bondOsingle bondSisingle bond covalent bond after the synthesis due to its reactive single bondSisingle bond(OCH3)3 head group, and thus makes the synthesized materials can be easily regenerated for reuse. The obtained materials show great potential in water treatment as pollutants sorbents.

Code

DOI: 10.1016/j.micromeso.2012.02.002

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