Graphene-Coated Hollow Fiber Membrane as the Cathode in Anaerobic Electrochemical Membrane Bioreactors - Effect of Configuration and Applied Voltage on Performance and Membrane Fouling

C.M. Werner, K.P. Katuri, H.A. Rao, W. Chen, Z. Lai, B.E. Logan, G.L. Amy, P.E. Saikaly
Environmental Science and Technology, Volume 50, Issue 8, pp. 4439-4447, (2016)

Graphene-Coated Hollow Fiber Membrane as the Cathode in Anaerobic Electrochemical Membrane Bioreactors - Effect of Configuration and Applied Voltage on Performance and Membrane Fouling

Keywords

Biofouling, Bioreactors, Cathodes, Electrodes, Graphene, Hydrogen production, Membrane fouling, Electrically conductive, Electrochemical membranes, Hollow fiber membranes, Membrane biofouling, Porous membranes, Reactor configuration, Reactor performance, Transmembrane pressures

Abstract

​Electrically conductive, graphene-coated, hollow-fiber porous membranes were used as cathodes in anaerobic electrochemical membrane bioreactors (AnEMBRs) operated at different applied voltages (0.7 and 0.9 V) using a new rectangular reactor configuration compared to a previous tubular design (0.7 V). The onset of biofouling was delayed and minimized in rectangular reactors operated at 0.9 V compared to those at 0.7 V due to higher rates of hydrogen production. Maximum transmembrane pressures for the rectangular reactor were only 0.10 bar (0.7 V) or 0.05 bar (0.9 V) after 56 days of operation compared to 0.46 bar (0.7 V) for the tubular reactor after 52 days. The thickness of the membrane biofouling layer was approximately 0.4 μm for rectangular reactors and 4 μm for the tubular reactor. Higher permeate quality (TSS = 0.05 mg/L) was achieved in the rectangular AnEMBR than that in the tubular AnEMBR (TSS = 17 mg/L), likely due to higher current densities that minimized the accumulation of cells in suspension. These results show that the new rectangular reactor design, which had increased rates of hydrogen production, successfully delayed the onset of cathode biofouling and improved reactor performance.​

Code

DOI: 10.1021/acs.est.5b02833

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